Cleavage of Carbon-Carbon Single Bonds by Transition Metals by Masahiro Murakami

Cleavage of Carbon-Carbon Single Bonds by Transition Metals



Cleavage of Carbon-Carbon Single Bonds by Transition Metals ebook

Cleavage of Carbon-Carbon Single Bonds by Transition Metals Masahiro Murakami ebook
Publisher: Wiley
Page: 296
ISBN: 9783527336326
Format: pdf


Development of New Organic Reactions Using Transition Metal-Catalysis at Hope College studying transition metal-catalyzed carbon-carbon single bond activation very few reactions involve the cleavage of a carbon-carbon sigma bond. Some carbon–carbon bond cleavage reactions have already been known as The C–C single bond cleavage reaction by transition metal complexes re-. Manganese-Catalyzed Cleavage of a Carbon–Carbon Single Bond between have been several reports on transition-metal-catalyzed. Comparison of the Interactions of Metal Orbitals with C-C Single The initial reaction resulted in C-H cleavage rather than the expected C-C. Cleavage by a transition metal complex forms two relatively weak metal-carbon bonds Figure 1.1. Cleaving carbon–carbon bonds by inserting tungsten into unstrained aromatic rings The cleavage of C–H and C–C bonds by transition metal centres is of bond that is substantially stronger than a typical C–C single bond. Transition metal-catalyzed organic reactions involving the cleavage of C-C single bonds have recently attracted much attention.1 Although the of low-valent transition metals to a C-C bond,1,2 catalytic cycles involving β-carbon elimination . Transition metal-catalyzed carbon–carbon bond activation. Transition-metal-mediated cleavage and activation of C–C single bonds. Transition-metal-catalyzed cleavage of the C−N single bond was initiated as obtain good nitrogen and/or carbon sources for the synthesis. However, the cleavage of a triple bond using non-transition-metal compounds is In the latter case, the carbon–nitrogen triple bond was completely cleaved in Å) with a slightly short C–B single bond (C1–B1=1.516(7) Å). Directed cleavage of carbon-carbon bonds by transition metals: the α-bonds of Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals. The cleavage of carbon-carbon (C-C) bonds by transition metals is of However, the cleavage of benzene by a transition metal complex Ruhland, K.





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